Spectrum Angular Width In the Phasmatron Spectroscope

Version 1.1 of 22/4/2010-3:11 p.m.

angular width diagram for two prisms

The following calculations assume you have read the analysis Calculating the Deviation Angle For A Prism.

Note that the first emergence angle at B is given by:

δ1=arcsin{sin(A)*sqrt(nλ2-sin21))-cos(A)*sin(α1)} (1)

For A=60°, and α1=60°, (1) gives:

δ1=arcsin{sqrt(3/2)*sqrt(nλ2-3/4)-sqrt(3/4)} => δ1=arcsin{sqrt(3/2)*(sqrt(nλ2-3/4)-1/2)} (2)

Now: 60°+δ12=180°=>α2=120°-δ1 (3)

=>α2=120°-arcsin{sqrt(3/2)*sqrt(nλ2-3/4)-sqrt(3/4)} (4)

Then with incidence angle α2 at C, the emergence angle at D will be:

δ2=arcsin{sqrt(3/2)*sqrt(nλ2-sin22))-sin(α2/2)} (5)

Concluding, first we calculate δ1 using (2), then we find α2 using (3) and finally compute δ2 from (5):

two prism angular width expressions

The method above generalizes to n prisms easily, provided we know the angles between them.

For example, we can calculate the spectrum's angular width Δδ2 that way:

for n=1.77578 for n=1.71681
δ1=65.446902° δ1=58.294643°
α2=54.553098° α2=61.705357°
δ2=73.569903° δ2=56.730209°

=>Δδ2=16.839694°.

Compare this with the ΔE we get from dE/dn=2/cos(arcsin(nD/2)). This formula gives for nD=1.72803, dE/dn=3.9724624 rad, so with a δ(n)=1.77578-1.71681=0.05898 we get ΔE=0.2342958 rad=13.424162°. The difference is understandable, since the formula for dE/dn is valid essentially only for the area of the sodium line D, from where we picked nD=1.72803.

CAUTION!: The width of the spectrum changes as we change the incidence angle.

For example: If α1=58°, then,

for n=1.77578 for n=1.71681
δ2=79.767447° δ2=58.593937°

With a Δδ2=21.17351°. If α1=62°, then,

for n=1.77578 for n=1.71681
δ2=69.773023° δ2=55.198486°

With a Δδ2=14.574537°.

Concluding, if the incidence angle is <60°, the spectrum is wider. If >60°, it is shorter. We take this into account later when we measure wavelengths. If we do not get the correct wavelength, it means that our collimator is not at 60° exactly.

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