The total deviation ε of a light ray can be computed, given the incidence angle α. The same calculation allows for determination of the emergence angle δ.
We have:
ε=ζ+η
A=β+γ
=>A+ε=(ζ+β)+(γ+η)
=>A+ε=α+δ
=>ε=α+δ-A (1)
sin(δ)/sin(β)=n=>δ=sin-1{n*sin(β)}
β=A-γ
=>δ=sin-1{n*sin(A-γ)} (2)
Now β=sin-1{sin(α)/n}, because sin(α)/sin(β)=n
again,
so (2)=>δ=sin-1{n*sin[A-sin-1(sin(α)/n)]}
(3)
Now sin[A-sin-1(sin(α)/n)]=sin(A)*cos(sin-1(sin(α)/n))-cos(A)*sin(α)/n
So δ=sin-1{n*sin(A)*cos(sin-1(sin(α)/n))-cos(A)*sin(α)}
=sin-1{n*sin(A)*Ö[1-(sin(α)/n)2]-cos(A)*sin(α)}
=>δ=sin-1{sin(A)*Ö[n2-sin2(α)]-cos(A)*sin(α)}
(4)
And finally:
(1)(4)=>
(5)
Here's a graph of the above equation, with A=60°, nD=1.72803 (SF10 Crystal) and α ranging from 45° to 80°. Angles are measured in degrees on the graph. Note that the deviation has a minimum, close to 60°.
For the position of minimum deviation, the ray travels perpendicular
to the bisect of angle A, and incidence and emergence angles are equal.
Then:
α=δ and β=γ (6)
Also: A=β+γ, εmin=(α-β)+(δ-γ)
(7)
(7)(6)=>A=2*β, εmin=2*α-2*β or
β=A/2 and εmin/2=α-A/2 => α=εmin/2+A/2 (8)
Now we know that n=sin(α)/sin(β) so from the last equation and
(8) we get:
(9)
For nD=1.72803 and A=60°, expression (9) gives εmin=59.54084145°, which is exactly the minimum displayed on the graph above.
Because the light dispersion angle is very small, (on the order of 7°) practically all the rays suffer minimum deviation. When a prism spectroscope is designed, its prism is placed in that position for usually the yellow part of the spectrum. (Sodium D lines). The PHASMATRON's prisms are placed in minimum deviation position for the green line of λ=5615.97363281Angstroms, its resonating wavelength.