The mechanical resolution is determined by the minimum angle ΔN by which the viewing telescope can turn. For the Phasmatron spectroscope's angle measuring devices, this is 10-3 degrees (a millionth of a degree). Converting to radians, ΔN=1.74532*10-5 rad. Next we need dE/dλ so we can approximate Δλ.
We know that dE/dn=2/cos{arcsin(nD/2)}. This for nD=1.72803 gives dE/dn=3.9724624 rad[1], and dn/dλ=1.2702*10-5/A[1], => dE/dλ=(dE/dn)*(dn/dλ)=5.04582*10-5 rad/A. Therefore we can approximate and use ΔE/Δλ=5.04582*10-5 rad/A, and since ΔE almost equals ΔN, Δλ=ΔN/5.04582*10-5 rad/A. For ΔN=1.74532*10-5 rad, this gives:
Δλmechanical=0.3458942A[1]. Compare this with Δλoptical=0.3866148A[1][2].
Suppose we wanted to calculate instead the mechanical resolution in the area of the blue Mercury line (4358.35A) Then:
dn/dλ=(1.76197-1.74805)/|4358.35-4799.9107|=3.1524545*10-5/A. dE/dn=2/cos{arcsin(n4358.35/2)}=4.22704 rad. dE/dλ=4.22704 rad*3.1524545*10-5/A=1.3325551*10-4 rad/A. Δλmechanical=1.74532*10-5 rad/1.3325551*10-4 rad/A=0.131A.
Compare this with Δλoptical=0.1152104A from Lord Rayleigh's formula Δλ=λ/{B*dn/dλ}, for dn/dλ=3.1524545*10-5/A, B=12*10-8A, and λ=4358.35A.
We observe that as a function of wavelength, the mechanical resolution varies roughly in the same way that the optical resolution does.